Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine
نویسندگان
چکیده
A mononuclear complex [MoOCl4(H2O)] readily forms a metal−metal bonded {Mo2O4} core. A high content of pyridine in the reaction mixture prevents further aggregation of dinuclear cores into larger clusters and a neutral, dinuclear complex with the [Mo2O4Cl2(Py)4] composition is isolated as a product. Solid state structures of two compounds containing this complex, [Mo2O4Cl2(Py)4]·2.25Py (1) and [Mo2O4Cl2(Py)4]·1.5PyHCl (2), were investigated by X-ray crystallography.
منابع مشابه
سنتز، شناسایی و ساختار بلوری کمپلکس دو هستهای مس (II) با لیگاند پلساز2،3،5،6 – تترا (2-پیریدل) پیرازین [{CuCl}2(μ – tppz)](PF6)2.
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